Environmental investigations show transuranic ions sorb to humic substances.
The resulting species are often mobile and are expected to be important
vectors in the migration of transuranic ions in natural systems. However,
theses environmental studies yield no quantitative data useful for modeling.
Laboratory complexation experiments with transuranic ions and humic
substances generate mermodynamic data required for complexation modeling.
The data presented in this work are based on the metal ion charge
neutralization model, which is briefly described. When a consistent
complexation model is used, similar results are obtained from different
experimental conditions, techniques, and laboratories. Trivalent transuranic
ions (CM(III), AM(III)) have been extensively studied with respect to pH,
ionic strength, origin of humic acid, and mixed species formation. The
complexation of Np(V) has been examined over a large pH and metal ion
concentration range with different humic acids. Some data does exist on the
complexation of plutonium with humic acid, however further work is needed.
Calculations on the Gorleben aquifer system using the thermodynamic data are
presented. Critical information lacking from the mermodynamic database is
identified.